Effective bimetallic composite catalysts for the synthesis of arylated furans and thiophenes in aqueous media

[Figure not available: see fulltext.] N-(4,6-Dimethylpyrimidin-2-yl)-5-phenylisoxazole-3-carboxamide was used as a ligand for obtaining bimetallic boron-containing heterogeneous catalysts Pd–Ni(Co)–B–L (Ni(Co):Pd = 9:1). The obtained composites were highly active as catalysts of Suzuki reaction in aqueous media, allowing to develop convenient methods for the synthesis of heterobiaryls containing furyl and thienyl rings. © 2019, Springer Science+Business Media, LLC, part of Springer Nature.

Authors
Bumagin N.A.1 , Petkevich S.K.2 , Kletskov A.V. 3 , Alekseyev R.S.1 , Potkin V.I.2
Publisher
Латвийский институт органического синтеза Латвийской академии наук / Springer New York Consultants Bureau
Language
English
Status
Published
Year
2019
Organizations
  • 1 M. V. Lomonosov Moscow State University, 1 Build. 3 Leninskie Gory, Moscow, 119991, Russian Federation
  • 2 Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov St, Minsk, 220072, Belarus
  • 3 RUDN University, 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation
Keywords
bimetallic catalyst; cobalt; furan; heterogeneous catalysis; isoxazole; nickel; palladium; pyrimidine; Suzuki reaction; thiophene
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