Cu(II) crown-tetraphenylporphyrinate: Molecular structure and evaluation of the formation of multinuclear complexes with s-metals

A novel neutral complex of a crown-fused tetraphenylporphyrin was obtained and its structure determined by X-ray analysis. Quantum chemical calculations were performed to establish the possibility of exploiting its crown units for the formation of multinuclear complexes with cations of alkaline and alkaline earth metals. © ISUCT Publishing.

Authors
Kotsuba V.E. 1 , Kolyadina N.N. 1 , Zubavichus Y.V.2 , Dorovatovskii P.V.2 , Khrustalev V.N. 1, 3
Number of issue
3
Language
English
Pages
234-237
Status
Published
Volume
9
Year
2016
Organizations
  • 1 RUDN University, Moscow, 117198, Russian Federation
  • 2 National Research Center “Kurchatov Institute”, Moscow, 123182, Russian Federation
  • 3 A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Keywords
Crown-porphyrins; Multinuclear complexes; Quantum chemical calculations; X-ray analysis
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