Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides

Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C–O coupling with further decarboxylation at 120 °C. © 2019

Authors
Bityukov O.V.1, 2 , Vil V.A.1, 2, 3 , Lukashin N.V.1, 3 , Cherednichenko A.G. 4 , Nikishin G.I.1 , Terent'ev A.O.1, 2, 3
Journal
Mendeleev Communications
Publisher
Royal Society of Chemistry
Number of issue
1
Language
English
Pages
55-56
Status
Published
Link
External link
DOI
10.1016/j.mencom.2019.01.017
Volume
29
Year
2019
Organizations
  • 1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
  • 2 All-Russian Research Institute for Phytopathology, Vyazyomy, Moscow Region B.143050, Russian Federation
  • 3 D. I. Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russian Federation
  • 4 Peoples Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
Date of creation
19.07.2019
Date of change
19.07.2019
Short link
https://repository.rudn.ru/en/records/article/record/39079/
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