PHYLOGEOGRAPHY AND POST-GLACIAL DYNAMICS IN THE CLONAL-SEXUAL ORCHID CYPRIPEDIUM CALCEOLUS L.
Article
Journal of Biogeography.
Blackwell Publishing Ltd.
Vol. 46.
2019.
P. 526-538
Intramolecular cascade annulation triggered by rhodium(III)catalyzed sequential C(sp 2 )–H activation and C(sp 3 )–H amination
A rhodium(III)-catalyzed intramolecular oxidative annulation of O-substituted N-hydroxyacrylamides for the construction of indolizinones via sequential C(sp 2 )–H activation and C(sp 3 )–H amination has been developed. This approach shows excellent functional-group tolerance. The synthesized scaffold forms the core of many natural products with pharmacological relevance. © 2019 Song et al.
Authors
Song L.1
,
Tian G.1
,
Van Der Eycken J. ,
Van Der Eycken E.V.
Publisher
Beilstein-Institut Zur Forderung der Chemischen Wissenschaften
Language
English
Pages
571-576
Status
Published
Link
Volume
15
Year
2019
Organizations
- 1 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium
- 2 Laboratory for Organic and Bio-Organic Synthesis, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281 (S.4), Ghent, B-9000, Belgium
- 3 Peoples’ Friendship University of Russia (RUDN University), Miklukho-Maklaya Street 6, Moscow, Russian Federation
Keywords
Acrylamide; Annulation; C–H activation; Heterocycles; Rhodium
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