Continuous-flow hydrogenation of methyl levulinate promoted by Zr-based mesoporous materials

Several Zr-based materials, including ZrO 2 and Zr-SBA-15, with different silicon/zirconium molar ratios, and ZrO 2 /Si-SBA-15 (where SBA-15 stands for Santa Barbara Amorphous material no. 15), have been prepared as hydrogenation catalysts. The materials were characterized using different characterization techniques including X-ray diffraction (XRD), N 2 porosimetry, scanning electron microscopy (SEM/EDX), diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) of pyridine adsorption and the pulsed chromatographic method using pyridine and 2,6-dimethylpyridine as probe molecules, mainly, have been employed for the characterization of the structural, textural, and acidic properties of the synthesized materials, respectively. The catalysts have been evaluated in the hydrogenation reaction of methyl levulinate using 2-propanol as hydrogen donor solvent. The reaction conditions were investigated and stablished at 30 bar system pressure with a reaction temperature of 200°C using around 0.1 g of catalyst and a flow rate of 0.2 mL/min flow rate of a 0.3 M methyl levulinate solution in 2-propanol. All catalysts employed in this work exhibited good catalytic activities under the investigated conditions, with conversion values in the 15-89% range and, especially, selectivity to γ-valerolactone in the range of 76-100% (after one hour time on stream). The highest methyl levulinate conversion and selectivity was achieved by ZrO 2 /Si-SBA-15 which can be explained by the higher dispersion of ZrO 2 particles together with a highest accessibility of the Zr sites as compared with other materials such as Zr-SBA-15, also investigated in this work. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.