Synthesis of 2,3-Bis[amino(benzylsulfanyl)methylidene]butanedinitrile and 2-(Benzylsulfanyl)pyridine-3-carbonitrile derivatives

The alkylation of cyanothioacetamide with benzyl chloride in DMF in the presence of 10% aqueous potassium hydroxide afforded 2,3-bis[amino(benzylsulfanyl)methylidene]butanedinitrile. Analogous reaction with addition of acetylacetone or its 3-methyl derivative led to the formation of 2-benzylsulfanyl-4,6-dimethylor -4,5,6-trimethylpyridine-3-carbonitrile. © 2018, Pleiades Publishing, Ltd.

Authors
Dyachenko I.V.1 , Dyachenko V.D.1 , Dorovatovskii P.V. 2 , Khrustalev V.N. 2, 3 , Torocheshnikov V.N.4 , Nenajdenko V.G. 4
Journal
Russian Journal of Organic Chemistry
Number of issue
12
Language
English
Pages
1785-1789
Status
Published
Link
External link
DOI
10.1134/S1070428018120072
Volume
54
Year
2018
Organizations
  • 1 Taras Shevchenko Lugansk National University, ul Oboronnaya 2, Lugansk, 92703, Ukraine
  • 2 National Research Center “Kurchatov Institute,”, pl. Akademika Kurchatova 1, Moscow, 123182, Russian Federation
  • 3 Peoples’ Friendship University of Russia, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 4 Faculty of Chemistry, Moscow State University, Leninskie gory 1, Moscow, 119991, Russian Federation
Date of creation
19.07.2019
Date of change
19.07.2019
Short link
https://repository.rudn.ru/en/records/article/record/38304/
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