A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity

A new “bicycle helmet”-like copper(ii),sodiumphenylsilsesquioxane Ph12Si12O12(OH)(O−)11Cu5Na(bipy)3(H2O) exhibited high catalytic efficiency in two homogeneous reactions: (i) functionalization of C-H compounds; (ii) formation of benzamides from alcohols. © The Royal Society of Chemistry.

Authors
Kulakova A.N. 1, 2 , Bilyachenko A.N. 1, 2 , Korlyukov A.A. 1, 3 , Shul'pina L.S.1 , Bantreil X. 4 , Lamaty F. 4 , Shubina E.S. 1 , Levitsky M.M. 1 , Ikonnikov N.S. 1 , Shul'pin G.B.5, 6
Journal
Dalton Transactions
Publisher
Royal Society of Chemistry
Number of issue
44
Language
English
Pages
15666-15669
Status
Published
Link
External link
DOI
10.1039/C8DT03209B
Volume
47
Year
2018
Organizations
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str. 28, Moscow, 119991, Russian Federation
  • 2 Peoples' Friendship University of Russia (RUDN University), Miklukho-Maklay Str. 6, Moscow, 117198, Russian Federation
  • 3 Pirogov Russian National Research Medical University, Ostrovitianov str. 1, Moscow, 117997, Russian Federation
  • 4 Institut des Biomolécules Max Mousseron (IBMM), UMR 5247, CNRS, Université de Montpellier ENSCM, Site Triolet Place Eugène Bataillon, Montpellier cedex 5, 34095, France
  • 5 Semenov Institute of Chemical Physics, Russian Academy of Sciences, ulitsa Kosygina dom 4, Moscow, 119991, Russian Federation
  • 6 Plekhanov Russian University of Economics, Stremyannyi pereulok dom 36, Moscow, 117997, Russian Federation
Keywords
Catalyst activity; Benzamides; Bicycle helmet; Catalytic efficiencies; Functionalizations; Homogeneous reaction; Copper compounds
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