Yugoslav Journal of Operations Research.
Vol. 17.
2007.
P. 149-164
Mixed-ligand palladium(II) complexes with amino acids, cytosine, and adenine
pH titration shows that 1 : 1 : 1 mixed-ligand complexes are formed in the systems palladium(II)-Cyt-Glu-H2O (loggB = 19.73) and palladium(II)-Cyt-Lys-H2O (logβ = 16.20). Complexes Pd(C 5H5N5)(C5H8NO 4)Cl, Pd(C5H5N5)(C6H 13N2O2)Cl, Pd(C4H5N 3O)(C6H13N2O2)Cl, and Pd(C4H5N3O)(C5H8NO 4)Cl are synthesized and characterized by chemical analysis, X-ray powder diffraction, and thermogravimetry. The coordination mode of amino acids, cytosine, and adenine to the palladium(II) ion is determined. © 2007 Pleiades Publishing, Inc.
Authors
Publisher
IAPC Nauka/Interperiodica
Number of issue
10
Language
English
Pages
1567-1569
Status
Published
Link
Volume
52
Year
2007
Organizations
- 1 Russian University of Peoples' Friendship, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
Keywords
Amino acids; Ligands; Synthesis (chemical); Thermogravimetric analysis; Titration; X ray powder diffraction; Coordination mode; Mixed-ligand complexes; Palladium(II) ion; PH titration; Palladium compounds
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Functional Analysis and its Applications.
Vol. 41.
2007.
P. 73-75