Synthesis and structure of complexes of some d metals with 10-(2-benzothiazolylazo)-9-phenanthrole (HL). Crystal and molecular structures of [CdL2] · DMF

The coordination compounds of cadmium(II), zinc(II), nickel(II), cobalt(II), and copper(II) with 10-(2-benzothiazolylazo)-9-phenanthrole (HL) were isolated in the crystalline state and studied. The crystal structure of the cadmium complex [CdL2] · DMF was determined by X-ray diffraction. The ligand is attached to cadmium in the form of anion functioning as an O,N,N-tridentate chelating ligand; this is accompanied by a change in its isomer form. The Cd configuration is a distorted octahedron. © 2013 Pleiades Publishing, Ltd.

Authors
Linko R.V. 1 , Sokol V.I.2 , Polyanskaya N.A. 1 , Ryabov M.A. 1 , Davydov V.V. 1 , Sergienko V.S.2
Journal
Russian Journal of Inorganic Chemistry
Publisher
IAPC Nauka/Interperiodica
Number of issue
2
Language
English
Pages
144-151
Status
Published
Link
External link
DOI
10.1134/S0036023613020150
Volume
58
Year
2013
Organizations
  • 1 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow 117198, Russian Federation
  • 2 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow 119991, Russian Federation
Keywords
Cobalt compounds; Copper compounds; Crystal structure; Crystalline materials; Ligands; Nickel compounds; Synthesis (chemical); X ray diffraction; Zinc compounds; Cadmium complex; Chelating ligands; Coordination compounds; Crystal and molecular structure; Crystalline state; Cadmium compounds
Date of creation
19.10.2018
Date of change
12.04.2021
Short link
https://repository.rudn.ru/en/records/article/record/2168/
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