Coordination Compounds of Uranyl Nitrate with Some Amide Ligands

Abstract: Six coordination compounds [UO2(L)2(NO3)2] were prepared by the reaction of UO2(NO3)2 with amide L (L = acetamide, N,N-dimethylacetamide, propanamide, valeramide, benzamide, N-methylurea) in water. The composition and the structure of the products were established by elemental analysis, IR spectroscopy, and powder and single-crystal X-ray diffraction. The molecular structure and the assignment of absorption bands for the obtained compounds were confirmed by quantum chemical calculations. © Pleiades Publishing, Ltd. 2025.

Авторы
Polukhin M.S. 1 , Savinkina Elena V. 1 , Karavaev Igor A. 1 , Akulinin Petr V. 1 , Buzanov Grigorii A. 2 , Kubasov A.S. 2 , Grigorév M.S. 3 , Strashnova Svetlana B. 4
Journal
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Номер выпуска
1
Язык
English
Страницы
58-67
Статус
Published
Ссылка
Внешняя ссылка
DOI
10.1134/S1070328424600931
Том
51
Год
2025
Организации
  • 1 MIREA - Russian Technological University (RTU MIREA), Moscow, Moscow Oblast, Russian Federation
  • 2 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
  • 3 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Moscow, Russian Federation
  • 4 Department of Mathematics, RUDN University, Moscow, Moscow Oblast, Russian Federation
Ключевые слова
acetamide; benzamide; N,N-dimethylacetamide; N-me-thy-lurea; propanamide; uranium; valeramide
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