Crystal structure and Hirshfeld surface analysis of dimethyl 4-hydroxy-5,4′-dimethyl-2′-(toluene-4-sulfonylamino)biphenyl-2,3-dicarboxylate

In the title compound, C25H25NO7S, the molecular conformation is stabilized by intramolecular O - H⋯O and N - H⋯O hydrogen bonds, which form S(6) and S(8) ring motifs, respectively. The molecules are bent at the S atom with a C - SO2 - NH - C torsion angle of -70.86 (11)°. In the crystal, molecules are linked by C - H⋯O and N - H⋯O hydrogen bonds, forming molecular layers parallel to the (100) plane. C - H⋯π interactions are observed between these layers. © 2024 International Union of Crystallography. All rights reserved.

Authors
Guliyeva N.A. , Burkin G.M. , Annadurdyyeva S. , Khrustalev V.N. , Atioǧlu Z. , Akkurt M. , Bhattarai A.
Publisher
International Union of Crystallography
Number of issue
Pt 1
Language
English
Pages
62-66
Status
Published
Volume
80
Year
2024
Organizations
  • 1 Department of Organic Substances and Technology of High-Molecular Compounds, SRI Geotechnological Problems of Oil, Gas and Chemistry, Azerbaijan State Oil and Industry University, Azadlig ave. 20, Baku, Az-1010, Azerbaijan
  • 2 RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 3 Zelinsky Institute of Organic, Chemistry of RAS, 4, 7 Leninsky Prospect, Moscow, 119991, Russian Federation
  • 4 Department of Aircraft Electrics and Electronics, School of Applied Sciences, Cappadocia University, Mustafapaşa, Ürgüp, Nevşehir, 50420, Turkey
  • 5 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 6 Department of Chemistry, M.M.A.M.C (Tribhuvan University) Biratnagar, Nepal
Keywords
arylsulfonamides; crystal structure; furan; Hirshfeld surface analysis; hydrogen bonds; [4 + 2] cycloaddition
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