Crystal structure and Hirshfeld surface analysis of 7-[(6-hydroxy-5,5,8a-trimethyl-2-methylenedecahydronaphthalen-1-yl)methoxy]-2H-chromen-2-one

The title compound, C24H30O4, consists of two trans-fused cyclohexane rings attached to a chromen-2-one moiety through an oxymethylene bridge. The cyclohexane rings adopt half-chair and chair conformations. In the crystal, molecules are linked by C-H...O and O-H...O hydrogen bonds, forming a triperiodic network. Furthermore, C-H...interactions stabilize the crystal structure. A Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H...H (56.9%), O...H/H...O (23.0%) and C...H/H...C (19.6%) contacts. © 2023 International Union of Crystallography. All rights reserved.

Authors
Karimli E.G. , Khrustalev V.N. , Akkurt M. , Khalilov A.N. , Bhattarai A. , Aleskerova A.N. , Mamedov I.G.
Journal
Acta Crystallographica Section E: Crystallographic Communications
Publisher
International Union of Crystallography
Language
English
Pages
777-781
Status
Published
Link
External link
DOI
10.1107/S2056989023006552
Volume
79
Year
2023
Organizations
  • 1 Azerbaijan Medical University, Bakikhanov st. 23, Baku, AZ1022, Azerbaijan
  • 2 Institute of Botany, Ministry of Science and Education of the Republic of Azerbaijan, Badamdar Highway 40, Baku, AZ1004, Azerbaijan
  • 3 Peoples' Friendship University of Russia, RUDN University, Miklukho-Maklay St. 6, Moscow, 117198, Russian Federation
  • 4 N. D. Zelinsky Institute of Organic Chemistry RAS, Leninsky Prosp. 47, Moscow, 119991, Russian Federation
  • 5 Department of Physics, Faculty of Sciences, Erciyes University, Kayseri, 38039, Turkey
  • 6 'Composite Materials' Scientific Research Center, Azerbaijan State Economic University (UNEC), H. Aliyev str. 135, Baku, AZ1063, Azerbaijan
  • 7 Department of Chemistry, Baku State University, Z. Khalilov str. 23, Baku, AZ1148, Azerbaijan
  • 8 Department of Chemistry, M.M.A.M.C. (Tribhuvan University) Biratnagar, Weil M. Vienna University of Technology, Austria
Keywords
C-H...interactions; crystal structure; Ferula persica; Hirshfeld surface analysis; hydrogen bonds
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