Amine adducts of triallylborane as highly reactive allylborating agents for Cu(i)-catalyzed allylation of chiral sulfinylimines

Convenient, atom-efficient allylation reagents with high selectivity and tunable reactivity, applicable to scale-up synthesis of homoallylamines.

Authors
Alexeev Michael S.1, 2 , Strelkova Tatiana V.1 , Ilyin Michael M.1 , Nelyubina Yulia V.1 , Bespalov Ivan A.3, 4 , Medvedev Michael G.1, 3 , Khrustalev Victor N. 3, 5 , Kuznetsov Nikolai Yu.1, 2
Journal
Organic and Biomolecular Chemistry
Publisher
Royal Society of Chemistry
Number of issue
23
Language
English
Pages
4680-4696
Status
Published
DOI
10.1039/d4ob00291a
Volume
22
Year
2024
Organizations
  • 1 A.N. Nesmeyanov Institute of Organoelement compounds, Russian Academy of Sciences, Vavilov st. 28, 119991 Moscow, Russian Federation
  • 2 A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russian Federation
  • 3 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 29, 119991 Moscow, Russian Federation
  • 4 Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, 119991, Russian Federation
  • 5 Peoples Friendship University of Russia, Miklukho-Maklay st. 6, 117198 Moscow, Russian Federation
Date of creation
16.09.2024
Date of change
16.09.2024
Short link
https://repository.rudn.ru/en/records/article/record/157508/
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