Bright luminescence of new low-melting copper(i) chlorides with compact organic cations

In this paper, we comprehensively studied two ACl/CuCl systems with dimethylammonium (DMA+) and acetamidinium (Ac+) organic cations and proved the formation of five new crystalline phases: DMACu2Cl3, DMACuCl2, DMA4[Cu2Cl6], DMA3CuCl4, and AcCuCl2.

Authors
Belikova Daria E.1 , Fateev Sergey A.1 , Khrustalev Victor N. 2, 3 , Kozhevnikova Vladislava4 , Ordinartsev Artem A.1 , Dzuban Alexander V.4 , Goodilin Eugene A.1, 4 , Tarasov Alexey B.1, 4
Journal
Journal of Materials Chemistry C
Publisher
Royal Society of Chemistry
Number of issue
34
Language
English
Pages
13537-13544
Status
Published
DOI
10.1039/D4TC02152E
Volume
12
Year
2024
Organizations
  • 1 Laboratory of New Materials for Solar Energetics, Faculty of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
  • 2 Inorganic Chemistry Department, Peoples’ Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation
  • 3 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, Moscow 119991, Russia
  • 4 Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
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