Crystal engineering of molecules with through-space α-effect hydrogen bonds: 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines possessing a free amino group

The existence of a “through-space” alpha-effect is analyzed in all-cis 3a,6 : 4,5 : 7,9a-triepoxy and 3a,6 : 7,9a-diepoxybenzo[de]isoquinolines. It is demonstrated that the H-bonds are enhanced by the α-effect.

Authors
Antonova A.S. 1 , Nikitina E.V. 1 , Valchuk K.S. 1 , Grigoriev M.S. 2 , Gomila R.M.3 , Frontera Antonio3 , Zubkov F.I. 1
Journal
CrystEngComm
Publisher
Royal Society of Chemistry
Number of issue
34
Language
English
Pages
6093-6100
Status
Published
Volume
24
Year
2022
Organizations
  • 1 A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky pr. 31, bld. 4, 119071 Moscow, Russian Federation
  • 2 Faculty of Science, Peoples' Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, 117198 Moscow, Russian Federation
  • 3 Department of Chemistry, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain
Date of creation
11.07.2024
Date of change
11.07.2024
Short link
https://repository.rudn.ru/en/records/article/record/155143/
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