Catalytic Synthesis of 1,2-Azole and Pyridine Derivatives of 1,8-Dioxooctahydroxanthenes Using FIBAN K-1 Fibrous Sulfonic Cation Exchanger

Arylmethylenebis(3-hydroxy-2-cyclohexen-1-ones) were obtained by condensation of 1,2-azole- and pyridine-substituted aromatic aldehydes of the vanillin series with 1,3-cyclohexanedione in methanol in the presence of trimethylamine. Catalytic cyclization using fibrous sulfocationite FIBAN K-1 gave corresponding 1,8-dioxooctahydroxanthenes.

Authors
Akishina E.A.1 , Dikusar E.A.1 , Polikarpov A.P.1 , Alekseeva K.A. 2 , Menshikova D.I. 2 , Kurman P.V.3 , Potkin V.I.1
Number of issue
3
Language
English
Pages
463-475
Status
Published
Volume
93
Year
2023
Organizations
  • 1 Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus
  • 2 Peoples’ Friendship University of Russia (RUDN University)
  • 3 Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus
Keywords
xanthenes; catalysis; sulfonic cation exchanger; isoxazole; isothiazole; pyridine; esters; Chemistry/Food Science; general
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