Synthesis and Structures of Mono- and Trinuclear Complexes of Palladium(II) with 2-Chloropyridine

New complex compounds[(2-clpy)2Pd(OOCMe)2] (I), [{(Ph)Pd(2-clpy)}2(OOCMe)4Pd]·3C6H6 (II), and [{(Ph)Pd(2-clpy)}2(OOCMe)4Pd] (III) are obtained in the interaction of palladium acetate [Pd3(OOCMe)6] with 2-chloropyridine (2-clpy) and structurally characterized by single crystal X-ray diffraction. It is found that in the inert medium, mononuclear compound I forms and it can be isolated in the crystalline state, while trinuclear complexes II and III are the products of benzene metalation with palladium under mild conditions.

Authors
Yakushev I.A.1 , Ogarkova N.K. 1, 2 , Sosunov E.A.1, 3 , Nesterenko M.Y.1, 3 , Kultyshkina E.K. 2 , Tereshina T.A. 2 , Popova A.S. 1, 2
Journal
Journal of Structural Chemistry
Number of issue
3
Language
English
Pages
377-385
Status
Published
Volume
64
Year
2023
Organizations
  • 1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
  • 2 Peoples’ Friendship University of Russia (RUDN University)
  • 3 Higher Chemical College of the Russian Academy of Sciences, Mendeleev University of Chemical Technology
Keywords
palladium; palladium acetate; 2-chloropyridine; carboxylates; polynuclear compounds; synthesis; single crystal X-ray diffraction analysis.; inorganic chemistry; physical chemistry; atomic; molecular; Optical and Plasma Physics; Atomic/Molecular Structure and Spectra; solid state physics
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