Triple role of thiocyanate-containing protic ionic liquids in chemodivergent ring-opening of 1,3-indanedione-derived donor–acceptor cyclopropanes

Triple-role thiocyanate-containing protic ionic liquids (PILs) were employed as a regenerable solvent, a Brønsted acid catalyst, and a source of the nucleophile for the ring-opening of 1,3-indanedione-based donor–acceptor cyclopropanes.

Authors
Ratmanova Nina K.1 , Andreev Ivan A.1 , Shcherbinin Vitaly A.2 , Ivanova Olga A.3 , Levina Irina I.4 , Khrustalev Victor N. 5 , Trushkov Igor V.2
Journal
Journal of Molecular Liquids
Publisher
Elsevier B.V.
Language
English
Pages
122401
Status
Published
DOI
10.1016/J.MOLLIQ.2023.122401
Volume
385
Year
2023
Organizations
  • 1 Dmitry Rogachev National Medical Research Center of Pediatric Hematology, Oncology and Immunology, Samory Mashela st. 1, 117997 Moscow, Russian Federation
  • 2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky pr. 47, 119334 Moscow, Russian Federation
  • 3 Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1-3, 119991 Moscow, Russian Federation
  • 4 N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Kosygina st. 4, 119334 Moscow, Russian Federation
  • 5 People's Friendship University of Russia (RUDN University), Miklukho-Maklaya st. 6, 117198 Moscow, Russian Federation
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