Exceptional structural diversity of hybrid halocuprates(i) with methylammonium and formamidinium cations

In this paper, MABr/CuBr and FABr/CuBr systems (MA+= methylammonium and FA+= formamidinium) were comprehensively studied: the existence of five novel phases MACu2Br3, FA2[Cu4Br6], MACuBr2, FACuBr2, and FA3CuBr4was established.

Authors
Belikova Daria E.1 , Fateev Sergey A.1 , Khrustalev Victor N. 2, 3 , Marchenko Ekaterina I.1, 4 , Goodilin Eugene A.1, 5 , Wang Shenghao6 , Tarasov Alexey B.1, 5
Journal
Dalton Transactions
Publisher
Royal Society of Chemistry
Number of issue
21
Language
English
Pages
7152-7160
Status
Published
DOI
10.1039/D3DT00687E
Volume
52
Year
2023
Organizations
  • 1 Laboratory of New Materials for Solar Energetics, Faculty of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
  • 2 Inorganic Chemistry Department, Peoples’ Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation
  • 3 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, Moscow 119991, Russia
  • 4 Department of Geology, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
  • 5 Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russian Federation
  • 6 Materials Genome Institute, Shanghai University, 99 Shangda Road, BaoShan District, Shanghai, 200444, China
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EFFECTS OF SYNTHESIS CONDITIONS ON THE CRYSTAL AND LOCAL STRUCTURES OF HIGH-ENTROPY OXIDES LN2M2O7 (LN = LA-YB, Y; M = TI, ZR, CE)

Article
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