Computational Optimization and Applications. Vol. 69. 2018. P.. 325-349
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings. © 2018, Pleiades Publishing, Ltd.
Authors
Cheplakova A.M. 1, 2 , Fedoseev I.S. 2 , Dorovatovskii P.V. 3 , Lazarenko V.A. 3 , Zubavichus Y.V. 3 , Khrustalev V.N. 4 , Fedin V.P. 1, 2
Issue number
2
Language
English
Pages
494-496
State
Published
Link
Volume
59
Year
2018
Organizations
- 1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
- 2 Novosibirsk State University, Novosibirsk, Russian Federation
- 3 National Research Center “Kurchatov Institute”, Moscow, Russian Federation
- 4 Peoples’ Friendship University of Russia, Moscow, Russian Federation
Keywords
coordination polymer; crystal structure; scandium complexes; tetrafluorobenzoic acid; tetrafluoroterephthalic acid
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