Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]

Novel square-planar Pt-based heterometallic complexes with ferrocenecarboxylic acid were prepared in two steps from (tetrapyridine)platinum diacetate [PtPy4](OAc)2. The crystal structure of [PtPy4](FcCOO)2 and [PtPy2(FcCOO)2] was established by single crystal X-ray diffraction. Subsequent thermal transformation of a trinuclear compound [PtPy2(FcCOO)2] to a bimetallic Pt–Fe phase was studied by XAFS techniques. © 2023

Authors
Yakushev I.A. , Ogarkova N.K. , Khramov E.V. , Smirnova N.S. , Yu. Nesterenko M. , Cherkashina N.V. , Medvedev A.G. , Panina M.V. , Vargaftik M.N. , Popova A.S.
Journal
Mendeleev Communications
Publisher
Royal Society of Chemistry
Issue number
4
Language
English
Pages
487-490
State
Published
Link
External link
DOI
10.1016/J.MENCOM.2023.06.015
Volume
33
Year
2023
Organizations
  • 1 N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
  • 2 Peoples’ Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
  • 3 National Research Center ‘Kurchatov Institute’, Moscow, 123182, Russian Federation
  • 4 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Keywords
ferrocenecarboxylic acid; platinum complexes; platinum–iron intermetallic compounds; thermolysis; X-ray absorption spectroscopy
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