Reaction Chemistry and Engineering. Vol. 8. 2022. P.. 152-163
Synthesis, structure and catalytic properties of Pdii-based bimetallic complexes with ferrocenecarboxylic acid
Novel highly soluble palladium-based complexes with ferrocenecarboxylic acid of general formula [Pd(lut)2(FcCOO)2] (lut is 2,6-or 3,4-lutidines) were synthesized and structurally characterized by single-crystal X-ray diffraction. The catalytic oxidation of 1,2-diphenyl-acetylene with these complexes gave dibenzo[a,e]pentalene derivative along with other products. © 2022
Authors
Popova A.S. , Ogarkova N.K. , Shapovalov S.S. , Skabitsky I.V. , Kultyshkina E.K. , A.Yakushev I. , Vargaftik M.N.
Journal
Publisher
Royal Society of Chemistry
Issue number
5
Language
English
Pages
576-578
State
Published
Link
Volume
32
Year
2022
Organizations
- 1 Peoples Friendship University of Russia (RUDN University), Moscow, 117198, Russian Federation
- 2 N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation
Keywords
dibenzo[a; diphenylacetylene; e]pentalene; ferrocenecarboxylic acid; homogeneous catalysis; ligand exchange; palladium complexes; XRD analysis
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