Synthesis, structure, and magnetic properties of bis(1-amino-9-hydroxy-4-azafluorenium) hexachlorocuprate(II) Cu2Cl6(C12H11N2O)(2)

The complex Cu2Cl6(C12H11N2O)(2) was synthesized by reacting copper(II) chloride crystal hydrate with 1-amino-9-hydroxy-4-azafluorene, and its crystal structure was determined. Cu2Cl6C12H11N2O)(2) is a centrosymmetric dimer with chlorine bridges, in which the organic ligand is coordinated to the copper atom through the oxygen atom of the hydroxyl group. The CuCl4O polyhedron is a distorted tetragonal pyramid in which the oxygen atom is in the axial position. In crystal, dimers are linked by hydrogen bonds to form a three-dimensional framework. The complex exhibits ferromagnetic properties, as was shown by EPR.

Авторы
Kuz'mina N.E. , Palkina K.K. , Polyakova N.V. , Golubev I.N. , Medvedev A.N. , Koval'chukova O.V. , Strashnova S.B. , Zaitsev B.E. , Levov A.N. , Toze F.
Редакторы
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Издательство
IAPC Nauka/Interperiodica
Номер выпуска
11
Язык
Английский
Страницы
1693-1697
Статус
Опубликовано
Подразделение
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Ссылка
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DOI
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Номер
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Том
47
Год
2002
Организации
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Ключевые слова
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Дата создания
19.10.2018
Дата изменения
19.10.2018
Постоянная ссылка
https://repository.rudn.ru/ru/records/article/record/8959/