The existing diversity of various scientific articles contains a large amount of information about complex structural catalysts of the NASICON type: a description of their catalytic properties, the usage of these catalysts in modern industry, as well as effective and reliable methods of their synthesis. Despite the large amount of information presented in scientific articles on this topic, the influence of catalytic centers in the structure of the catalyst, as well as the structure itself, on the processes of converting alcohols into industrially important components has not been clearly established. Based on a detailed analysis of 87 researches of catalysts with the NASICON structure, this review presents a modern and concise analysis of the field of research of these structures, in particular, how researchers studied the methods of synthesis of these complex systems, the catalytic properties of catalysts, as well as their environmentally safe application in modern industry. The studied and analyzed data contain a large amount of information about the physical and chemical properties of complex catalysts of the NASICON type. In addition to describing the impact of catalytic data centers of systems, as well as their structure, the review summarized and structured information that will allow scientists and researchers to refine or create effective and environmentally friendly ways to use NASICON catalysts in the processes of converting alcohols to obtain industrially important objects.