Synthesis, structure, and magnetic properties of bis(1-amino-9-hydroxy-4-azafluorenium) hexachlorocuprate(II) Cu2Cl6(C12H11N2O)(2)

The complex Cu2Cl6(C12H11N2O)(2) was synthesized by reacting copper(II) chloride crystal hydrate with 1-amino-9-hydroxy-4-azafluorene, and its crystal structure was determined. Cu2Cl6C12H11N2O)(2) is a centrosymmetric dimer with chlorine bridges, in which the organic ligand is coordinated to the copper atom through the oxygen atom of the hydroxyl group. The CuCl4O polyhedron is a distorted tetragonal pyramid in which the oxygen atom is in the axial position. In crystal, dimers are linked by hydrogen bonds to form a three-dimensional framework. The complex exhibits ferromagnetic properties, as was shown by EPR.

Authors
Kuz'mina N.E. , Palkina K.K. , Polyakova N.V. , Golubev I.N. , Medvedev A.N. , Koval'chukova O.V. , Strashnova S.B. , Zaitsev B.E. , Levov A.N. , Toze F.
Editors
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Publisher
IAPC Nauka/Interperiodica
Number of issue
11
Language
English
Pages
1693-1697
Status
Published
Department
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Link
-
DOI
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Number
-
Volume
47
Year
2002
Organizations
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Keywords
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Date of creation
19.10.2018
Date of change
19.10.2018
Short link
https://repository.rudn.ru/en/records/article/record/8959/