Handbook of Environmental Chemistry.
Springer Verlag.
Vol. 52.
2017.
P. 17-24
Ruthenium-catalysed one-pot regio- and diastereoselective synthesis of pyrrolo[1,2-a] indoles via cascade C-H functionalization/annulation
A cascade approach has been developed towards dual C-C bond formation via consecutive C-H functionalization/cyclization giving access to pyrrolo[1,2-a]indoles in a highly regio- and diastereoselective manner using catalytic [Ru(p-cymene)Cl2]2. The methodology was further expanded to attain pentacyclic structures involving manifold C-C bond creation. © 2017 The Royal Society of Chemistry.
Authors
Singh S.1
,
Butani H.H.1,
2
,
Vachhani D.D.2
,
Shah A.2
,
Van Der Eycken E.V.
Journal
Publisher
Royal Society of Chemistry
Number of issue
78
Language
English
Pages
10812-10815
Status
Published
Link
Volume
53
Year
2017
Organizations
- 1 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven, KU Leuven, Celestijnenlaan 200F, Leuven, B-3001, Belgium
- 2 Department of Chemistry, Saurashtra University, Rajkot, India
- 3 Peoples Friendship University of Russia, RUDN University, Miklukho-Maklaya street 6, Moscow, 117198, Russian Federation
Keywords
carbon; hydrogen; indole derivative; pyrrolo[1,2 a]indole derivative; ruthenium; unclassified drug; annulation reaction; Article; catalysis; chemical reaction; diastereoisomer; functionalization reaction; hydrogen bond; Michael addition; one pot synthesis; regioselectivity; stereoselectivity
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