Sovremennye Problemy Distantsionnogo Zondirovaniya Zemli iz Kosmosa.
Space Research Institute of the Russian Academy of Sciences.
Vol. 14.
2017.
P. 210-221
Unusual regioselectivity of C1[sbnd]C70(CF3)10 in the Diels-Alder reaction
The Diels-Alder reaction of C1[sbnd]C70(CF3)10 and butadiene sulfone yielded 82 mol% from starting material of single C70(CF3)10C4H6 regioisomer. The optimization of the synthesis conditions C70(CF3)10C4H6: varied concentration and ratio of reagents, synthesis time. The new compound was characterized by using 1H, 1D and 2D 19F NMR; IR and UV–vis spectroscopy; electro-spray ionization mass spectrometry and DFT calculations. © 2016 Elsevier B.V.
Authors
Nekrasov V.M.1,
2
,
Dutlov A.E.1,
2
,
Trubitsyn M.G.1
,
Kotov A.I.1
,
Martynenko V.M.1
,
Barzilovich P.Y.1
,
Korchagin D.V.
1,
3
,
Bubnov V.P.1
,
Kareev I.E.1
Journal
Publisher
Elsevier B.V.
Language
English
Pages
81-87
Status
Published
Link
Volume
196
Year
2017
Organizations
- 1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russian Federation
- 2 Department of Fundamental Physics and Chemical Engineering, M. V. Lomonosov Moscow State University, Moscow, 119991, Russian Federation
- 3 RUDN University, 6 Miklukho-Maklaya st, Moscow, 117198, Russian Federation
Keywords
Butadiene sulfone; C70; Fullerene; Trifluoromethyl iodide; Trifluoromethylation
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Communications in Computer and Information Science.
Springer Verlag.
Vol. 700.
2017.
P. 120-134