Hibiscus Rosasinensis L. aqueous extract-assisted valorization of lignin: Preparation of magnetically reusable Pd NPs@Fe3O4-lignin for Cr(VI) reduction and Suzuki-Miyaura reaction in eco-friendly media

Hibiscus Rosasinensis L. extract mediated biosynthesis of Pd nanoparticles (NPs) and their deposition on the magnetic calcium lignosulfonate (MCaLig), as a simple and eco-friendly process for the preparation of Pd NPs@Fe3O4-lignin, is reported. The Pd NPs@Fe3O4-lignin was characterized by TEM, XRD, EDS, FE-SEM, FT-IR, VSM, and UV–Vis. The magnetic NPs were employed as exceptional catalysts in the catalytic reduction of Cr(VI) and Suzuki-Miyaura reaction between PhB(OH)2 and substituted aryl halides in EtOH:H2O as well as under ligand free conditions in the presence of K2CO3 with satisfactory product yields. Regeneration of the Pd NPs@Fe3O4-lignin was carried out by a magnet after the preparation of biphenyls. Catalytic efficiency retention was achieved after seven cycles. © 2020 Elsevier B.V.

Authors
Nasrollahzadeh M.1 , Bidgoli N.S.S.1 , Issaabadi Z.1 , Ghavamifar Z.1 , Baran T.2 , Luque R. 3, 4
Journal
International Journal of Biological Macromolecules
Publisher
Elsevier B.V.
Language
English
Pages
265-275
Status
Published
Link
External link
DOI
10.1016/j.ijbiomac.2020.01.107
Volume
148
Year
2020
Organizations
  • 1 Department of Chemistry, Faculty of Science, University of Qom, Qom, 3716146611, Iran
  • 2 Aksaray University, Faculty of Science and Letters, Department of Chemistry, Aksaray, 68100, Turkey
  • 3 Departamento de Quimica Organica, Universidad de Cordoba, Campus de Rabanales, Ctra Nnal IV-A, Km 396, Cordoba, E14014, Spain
  • 4 Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya str., Moscow, 117198, Russian Federation
Keywords
Biowaste; Cr(VI) reduction; Hibiscus Rosasinensis L.; Pd NPs@Fe3O4-lignin; Suzuki-Miyaura
Date of creation
10.02.2020
Date of change
10.02.2020
Short link
https://repository.rudn.ru/en/records/article/record/56500/
Share

Other records