Synthesis of dienes with tetrafluorophenylene bridge based on the catalytic olefination reaction. New promising monomers for the design of molecular architectures with halogen—halogen interactions

Catalytic olefination of tetrafluoroterephthalic aldehyde hydrazone was studied. Dienes with a tetrafluorophenylene bridge containing different substituents at the double bonds were obtained. Stereochemistry of the reaction, as well as molecular structure and crystal packing of the dienes were studied. © 2016, Springer Science+Business Media New York.

Authors
Muzalevskiy V.M.1 , Magerramov A.M.2 , Shihaliev N.G.2 , Balenkova E.S.1 , Shastin A.V.3 , Dorovatovskiy P.V.4 , Zubavichus Y.V.4 , Khrustalev V.N. 5, 6 , Nenajdenko V.G.1
Journal
Russian Chemical Bulletin
Number of issue
6
Language
English
Pages
1541-1549
Status
Published
Link
External link
DOI
10.1007/S11172-016-1480-2
Volume
65
Year
2016
Organizations
  • 1 Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, Moscow, 119991, Russian Federation
  • 2 Department of Chemistry, Baku State University, 23 ul. Akad. Z. Halilova, Baku, AZ1148, Azerbaijan
  • 3 Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432, Russian Federation
  • 4 Scientific Research Center “Kurchatov Institute”, 1 pl. Akad. Kurchatova, Moscow, 123182, Russian Federation
  • 5 Peoples’ Frendship University of Russia, 6 ul. Miklukho-Maklaya, Moscow, 117198, Russian Federation
  • 6 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, Moscow, 119991, Russian Federation
Keywords
alkenes; catalytic olefination; dienes; fluorine; halogen—halogen interactions; polyhaloalkanes; trifluoromethyl
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