The influence of plasma chemical treatments on the activity of the Li 3Fe2(PO4)3 catalyst in butanol-2 transformations

The influence of plasma chemical treatments in oxygen, hydrogen, and argon on the catalytic activity of Li3Fe2(PO4) 3 was studied for the example of butanol-2 transformations. Plasma chemical treatment was found to be an effective method for increasing catalyst activity and changing its selectivity. The character of activation depends on the selection of the plasma-forming gas. The highest activity in the dehydration of butanol-2 was observed after treating the catalyst in hydrogen under glow discharge conditions. © Nauka/Interperiodica 2006.

Authors
Pylinina A.I. 1 , Mikhalenko I.I. 1 , Ivanov-Shits A.K.2 , Yagodovskaya T.V. 3 , Lunin V.V.3
Journal
Russian Journal of Physical Chemistry A
Number of issue
6
Language
English
Pages
882-885
Status
Published
Link
External link
DOI
10.1134/S0036024406060070
Volume
80
Year
2006
Organizations
  • 1 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russian Federation
  • 2 Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russian Federation
  • 3 Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119899, Russian Federation
Keywords
Alcohols; Catalyst activity; Catalyst selectivity; Chemical activation; Dehydration; Glow discharges; Iron compounds; Fe2; Li3; Plasma chemical treatments; Plasma forming gas; Lithium compounds
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