The electrochemical insertion of alkali metals in transition metal monoxides

Electrochemical insertion of lithium was observed in monoxides ScO, TiO, and VO. The diffusion coefficient in ScO and TiO is 10-14-10-11 cm2 s-1 and in VO, it is 1-3 orders of magnitude smaller. No insertion of lithium in NbO was observed. Sodium does not enter these components at all. © 1990.

Authors
Vondrák J.1 , Bludská J.1 , Belan V.N.2 , Lazarev V.B.2 , Bogatov Yu.E. 3
Journal
Electrochimica Acta
Number of issue
1
Language
English
Pages
17-23
Status
Published
Link
External link
DOI
10.1016/0013-4686(90)85030-Q
Volume
35
Year
1990
Organizations
  • 1 Institute of Inorganic Chemistry, Czechoslovak Academy of Science, Majakovskeho 24, 16000 Praha 6, Czech Republic
  • 2 Institute of General and Inorganic Chemistry, Academy of Science, U.S.S.R., Moscow, Russian Federation
  • 3 Patrice Lumumba University of Friendship of Nations, Russian Federation
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